Pulp bleaching process pdf

To the extent that these pulps are bleached, hydrogen peroxide or some. Corrosive chemical are often used for this purpose. Brightness is a measure used to tell how white the pulp appears. These courses cover pulp bleaching processes and concepts. Cn102776795b application of organic phosphonic acid in pulp. Andritz highconsistency bleaching systems providing maximum brightness with minimum chemical consumption for sc, lwc, improved newsprint, and bleached board grades andritz, one of the market leaders for highconsistency bleach plants, offers the optimum bleaching system for specific needs. Pdf kraft pulp bleaching with hydrogen peroxide and peracetic acid. The chemical reactions in kraft pulping process pulp paper mill.

They produce many hazard organic compounds such as organic halides during bleaching process. Then the whole bleaching sequence is based on the use of clo2 only. To provide a complete description of the bleaching process, the needed relationships from mill operating data. Deded type process even though some oxygen and hydrogen peroxide are often added. Model predictive control of a mechanical pulp bleaching process. Pulp tracking is a concept that can track the performance of various key pulp properties through the process, such as moisture content in wood chips, pulp conductivity in brown stock washers, or chemical dosage in the first stage of bleaching. Pulpingnew technology in pulping and bleaching 91 9 much of the chemical pulping industry is focused on use of the kraft pulping process, and efforts to make the process more efficient continue.

Mechanical, semichemical, and sulfite pulp mills differ in detail, particularly in wood preparation, fiber separation, and bleaching, but many of the downstream refining. The preferred ph for the process isa more preferred range is 6. Paper pulp bleaching process pulp bleaching equipments. The kappa number is directly proportional to the lignin content of the pulp. After cooking process and washing process, the paper pulp is brown. The link between manganese content in an oxygendelignified pulp and peroxide bleaching efficiency is shown in table 11. Bleaching is important for the production of not only white but also colored paper since a bleached surface is needed for dyeing.

Brightness is measured by calculating the amount of blue light that reflects off the surface of a pulp handsheet sample. A membrane hybrid process of nanofiltration nf and electrodialysis ed is optimised to recover water from the e1 alkaline pulp bleaching effluent. Commercial processes are generally classified as mechanical, chemical, or semi. Compared with the unbleached pulp, the wrv and strength properties of the bleached pulp increased after each bleaching process.

Elemental chlorine ec reacts selectively with the non carbohydrate compounds. Paper made with woodbased pulp is brown in its natural state think paper grocery bags. Environmental protection agency epa as being the best available technology to bleach paper products. Bleaching is the treatment of cellulosic fiber with chemicals to increase brightness see box 4a. Lignin remains a major constituent of pulp even after digestion by chemical pulping. Pdf this work evaluates the findings of various research efforts and describes the. Method of bleaching paper pulp download pdf info publication number ep0587270b1. The kraft process also known as kraft pulping or sulfate process is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibers, the main component of paper. Extraction delignification process variables for ecf sequences.

The invention relates to an application of organic phosphonic acid in a pulp bleaching process. The primary product of wood pulp is paper, for which whiteness similar to, but distinct from brightness is an important characteristic. Ecf bleaching processes provide several pulp quality advantages relative to tcf. The paper making process, the fifth technical brochure from sappi idea exchange idea exchange sappi is committed to helping printers and graphic designers use paper in the best possible way.

The efficacy and robustness of our new technique is demonstrated by controlling the pulp bleaching process using an indirect adaptive model predictive control algorithm with a recursive least. Brown paper pulp presents no problem for certain uses, for example, sack paper, most corrugated boxes, some bag paper and so on. In modern world most of the pulp is manufactured by kraft pulping process. Our online pulp bleaching training courses provide essential training for pulp manufacturing. Authority ep european patent office prior art keywords pulp process according added wt sodium prior art date 19920618 legal status the legal status is an assumption and is not a legal conclusion. Pulp bleaching processing means that make the coloring materials of the pulp are removed or modified to a certain degree. Hypochlorite 5% on pulp bleaching reduces the yield to 42%. The bleaching treatment can be made with sodium chloride, which can result in cellulose degradation saheb 1999, and different properties and characteristics of cellulose can arise. Continuous operating bleaching introduced by thorne in multistage bleaching for purification of pulp from demand for large tonnages of nitrocellulose during wwi 2 stage hypochlorite then added alkaline extraction in between hypochlorite stages use of chlorine dioxide investigated from.

Pdf oxidative and reductive bleaching of deinked pulp. Comparative evaluations demonstrated that treated effluents from the two. Pulp and paper manufacturing processes in papermaking industry. Bleaching and the environment why pulp is bleached much pulp is used in its unbleached form, particularly for packaging and industrial papers, for some tissues and for newsprint. Pulp and paper pulp is the fibrous mass that results when a pulping process ruptures the bonds in the wood structure that hold the woody cells together. Pulp and paper, bleaching and brightening, modeling and control, optimization.

These processes and chemistry are also applicable to the bleaching of nonwood pulps, such as those made from bamboo or kenaf. Before adding bleaching chemicals, the pulp was pre. Facts about the use of bleaching agents in tissue and paper. Domestically, ecf bleaching is recognized by the u. This module provides a brief background on wood fibers and chemical pulping, and then provides information on what bleaching is and how it fits into the papermaking process. Bleaching process during paper production is the chief source of. Google has not performed a legal analysis and makes no. Pulp bleaching is the process by which pulped wood particles are brightened or whitened.

Box 4000, fin90014 university of oulu, finland, department of process and environmental engineering, university of oulu, p. Pratima bajpai, in environmentally benign approaches for pulp bleaching second edition, 2012. Pdf process water recovery from pulp bleaching effluents. Nedmag focuses on modernising existing bleaching formulas. Milichovsky department of wood, pulp, and paper, faculty of chemical technology, university of pardubice, cz532 10 pardubice, czech republic received 19 may 2000 laboratory bleaching studies were carried out on kraft pulp to investigate the in. The pulp then proceeds through various stages of washing, and possibly bleaching, after which it is pressed and dried into the finished product. This process uses 8% sodium sulfite and 2%3% sodium carbonate on dry straw, with a liquor to straw ratio of 7. Bleaching process an overview sciencedirect topics. The oxygen, ozone, hydrogen peroxide and chlorine dioxide are more environmentally bleaching agent compatible to chlorine and they reduces significantly the consumption of chlorine.

Therefore, many leading pulp mills modify their bleaching sequences so that it can be decreased the impact on environment. Pulp and paper mills are highly complex and integrate many different process areas including wood preparation, pulping, chemical recovery, bleaching, and papermaking to convert wood to the final product. Competitiveness benefits potential for energy savings up to 147 billion btu per year for each. Pulp bleaching technology the bleaching process bleaching is the treatment of cellulosic fiber with chemicals to increase brightness see box 4a. The process also contributes to the chemical balance of the finished paper product and removes dirt and foreign particles. Thus, in this work, the sugarcane pulping and bleaching were investigated using. The hydrogen peroxide bleaching process p stage was conducted at 10% pulp consistency with 2. A serious shortcoming of the fungal bleaching process is the long incubation time required for contact with the biomass. The kraft process entails treatment of wood chips with a hot mixture of water, sodium hydroxide naoh, and sodium sulfide na 2 s, known as white liquor, that breaks the bonds that link lignin.

Steps in the pulp and papermaking process raw material preparation wood received at a pulp mill may be in several different forms, depending on the pulping process. Finally, as the main byproduct of ozone chemistry is oxygen, it is an ideal choice to limit the formation of chlorinated byproducts aox formed during conventional bleaching processes. How pulp bleaching works bleaching paper pulp mixer direct. Jan 18, 2018 next the pulp is sent through filters. Faubert an oxygenclielationperoide oqe eopqp or qeopp sequence brightened a kraft pulp to an is0 brightness of 70%, provided that the kappa number of the pulp entering the peroxide stage was below 17. Tcdd 2,3,7,8tetrachlorodibenzopdioxin may be formed during the chlorine bleaching process used by pulp and paper mills, and as a contaminant in the manufacturing process of. Pdf pollution reduction from pulp bleaching effluents by. Pulping is done mechanically, thermomechanically, chemically, or with combinations of these treatments. Both unbleached and bleached pulp is produced to meet the requirement of paper. It ruptures the lignin bonds and make important amount of chlorinated organic.

The organic phosphonic acid is prepared by heating diethylenetriamine pentamethyl phosphonic acid, amino trimethylene phosphonic acid and polyacrylic acid to 65 deg c75 deg c by a reaction kettle according to the mass ratio of 0. Reeve, this book contains the work of 57 coauthors and was sponsored by the pulp bleac hing. Advantages and disadvantages of oxygen delignification 2. Kraft process variability reduction in pulping, washing. Pulp bleaching basic principles convergence training.

The woodbased pulping and bleaching process is very, very wellbalanced at least at large scale. Ep0679760b1 ep94203640a ep94203640a ep0679760b1 ep 0679760 b1 ep0679760 b1 ep 0679760b1 ep 94203640 a ep94203640 a ep 94203640a ep 94203640 a ep94203640 a ep 94203640a ep 0679760 b1 ep0679760 b1 ep 0679760b1 authority ep european patent office prior art keywords pulp up magnesium calcium ph prior art date 19910430 legal status the legal status is an assumption. This process uses 8% sodium sulfite and 2%3% sodium carbonate on dry straw, with a liquor to straw ratio of. Mar 26, 2015 the approximate brightness of unbleached kraft pulp range is 1530, whereas sulfite pulp range is 5065. First commercially viable kraft mill, sweden, 1885. Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten the pulp. After the acid has been sprayed onto the pulp a xylanase enzyme made by t. The desired brightness and whiteness of many finished paper products is achieved through a bleaching stage in the paper manufacturing process. Pdf laboratory bleaching studies were carried out on kraft pulp to. The pulp is not only made of cellulose and hemicelluloses, but it also contains some impurities which are never completely removed in the pulping process. Jun 30, 2015 kraft pulping process is the most used pulping process in the world. Bleaching pulp and bleach solution must be oxygenfree careful ph control of pulp and bleaching solution, must avoid phs below 5 or above 7 sodium hydrosulfite should be freshly made, if stored, should be at low temperature. Box 4300, fin90014 university of oulu, finland 2005 oulu, finland abstract. Kraft pulp bleaching with hydrogen peroxide and peracetic.

Oct 19, 2019 after the acid has been sprayed onto the pulp a xylanase enzyme made by t. Paper pulp bleaching and pulp bleaching equipments. The process uses oxygen to reduce active chlorine requirements in the bleach plant, and is an important step towards total chlorine free tcf and elemental chlorine free ecf pulp production. The blow of the digester does not apply to continuous digester systems.

So we share our knowledge with customers, providing them with samples, specifications, ideas, technical information and a complete range of brochures. Ep0679760b1 process for bleaching of lignocellulose. With chlorine gradually being phased out of the bleaching process, and oxygen being the least expensive bleaching chemical in the mill, oxygen delignification offers significant operating cost advantages over delignification processes which use bleaching agents such as chlorine dioxide and hydrogen peroxide. It enabled the recovery and reuse of the inorganic pulping chemicals such that a kraft mill is a nearly closedcycle process with respect to inorganic chemicals, apart from those used in the bleaching process. Pulp bleaching processing plays an important role in paper making, it is mainly used to improve lightness of paper pulp and get quality pulp with certain whiteness, cleanliness, purity and excellent. Better control of production costs and process efficiency, attainment of evolv ing product quality specifications, and minimization of efflu ent volume and air emissions were the result. The oxygen, ozone, hydrogen peroxide and chlorine dioxide are more environmentally bleaching agent compatible to chlorine and they reduces significantly the. Chlorination bleaching is the second stage of the pulp bleaching process. Very little mechanical pulp has been bleached in the past, however, this is currently changing. Hydrogen peroxide bleaching process p stage the hydrogen peroxide bleaching process p stage was conducted at 10% pulp consistency with 2. The distinction is made between brightening and bleaching but the term bleaching. A typical layout of a mill using the kraft chemical pulping process is shown in figure 21. Lignin imparts a color to the raw pulp hence its name brown stock and unless removed, will continue to darken with age note the yellowing.

These process variables are tracked in space and time up to the location of interest. Recently, oxygen delignification has been recognized as one of the strategic technologies which offer yield. These simulations are used to minimize bleaching and pulp production. In the paper industry, bleaching pulp is of great importance to produce good quality paper. Kraft pulp bleaching with hydrogen peroxide and peracetic acid. The primary product of wood pulp is paper, for which whiteness is an important characteristic. Not surprisingly, the mix of these pressures, in conjunction with a host kraft ecf pulp bleaching. In this process lignin goes into the reactions with the cooking liquor chemicals and split into fragment. Brightness may be achieved by either lignin removal delignification or lignin decolonization. Mechanical pulping processes retain the lignin to obtain a higher yield. Hu fpinnovations pulp and paper division 3800 wesbrook mall, vancouver, bc v6s 2l9. Pulp and paper manufacturing process in the paper industry. Magnesium hydroxide is an innovative product which allows for environmentally friendly pulp bleaching.

After cooking process, washing process and bleaching process, the pulp is then sent to the paper plant. Basic overview of pulp and paper manufacturing process. Bleaching is often undertaken, primarily for two purposes. To be used as kraft paper for corrugated cardboard, they are sent directly to the papermaking process without bleaching. Chemical pulps are bleached by the addition of chemicals such as chlorine, chlorine dioxide or hypochlorite. The removal of lignin by bleaching is regarded as a continuation of the pulping process, albeit somewhat gentler and less destructive, but bleaching too can degrade cellulose if done improperly. Aronovsky 1948 suggested an nssc process for pulping wheat straw. This highly coloured effluent has a high content of organic and organochlorinated compounds and. To measure the lignin content in pulp, a number called the kappa number is used. Pdf the pulp bleaching following depd and oded sequences has been studied for pollution load reduction in the effluents. Pulp bleaching process comprising oxygen delignification and xylanase enzyme treatment. Tcdd 2,3,7,8tetrachlorodibenzopdioxin may be formed during the chlorine bleaching process used by pulp and paper mills, and as a contaminant in the manufacturing process of certain chlorinated organic chemicals. It is the cheapest bleaching agent for eliminating lignin. Learning objectives identify and describe key equipment used in bleaching operations.

However, optimally and cost effectively setting up the process is a continuous challenge. Raw pulp contains an appreciable amount of lignin and other discoloration, it must be bleached to produce light colored or white papers preferred for many products. Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten. For this reason, in the 1940s, the kraft process superseded the sulfite process as the dominant method for producing wood pulp. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed. Facts about the use of bleaching agents in tissue and. In the second stage after refining, the pulp is screened, cleaned, and most of the process water is removed in preparation for paper making.

Kraft pulp bleaching with hydrogen peroxide and peracetic acid f. In practice, there are two separate bleaching process steps. Introduction pulp used in the paper making process can be made whiter by several methods. Sillanpaa, mervi, studies on washing in kraft pulp bleaching faculty of technology, university of oulu, p. Mechanical pulp bleaching is growing at more than twice the rate of chemical pulp bleaching worldwide and it is. Pollution reduction from pulp bleaching effluents by process change article pdf available in ippta. Through several industrial results, this work describes process improvements in ozone bleaching since 1992, and shows results obtained for pulp quality and bleaching chemical costs from modern bleaching fiberlines including one mill located in india. The process wastewater containing chlorinated pollutants and other.

Quarterly journal of indian pulp and paper technical association 292 april 2017 with 270. Oxygen is cheaper than chlorine dioxide and hydrogen peroxide. The balance of the kraft process is designed to recover the cooking chemicals. The pulp and paper making processes princeton university. The pulp is next put through a pounding and squeezing process called, appropriately enough, beating. Wood pulping papermaking chemical recovery boiler spent chemicals lignin steam electricity regenerated chemicals a damn good system cellulose. Chlorine and chlorine dioxide are conventionally used with process water to bleach pulp. These fragments dissolved with the solution and wood disintegrates into fiber.